array(2) { ["lab"]=> string(4) "1409" ["publication"]=> string(5) "12494" } Arylchlorogermanes/TBAF/“Moist” Toluene: A Promising Combination for Pd-Catalyzed Germyl-Stille Cross-Coupling - Liang Yong | LabXing

Liang Yong

简介 中藥質量控制資訊系統，生物資訊學

大学 Macau University of Science and Technology / Faculty of Information Technology
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Arylchlorogermanes/TBAF/“Moist” Toluene: A Promising Combination for Pd-Catalyzed Germyl-Stille Cross-Coupling

2010
期刊 Organic letters
The trichlorophenyl,- dichlorodiphenyl,- and chlorotriphenylgermanes undergo Pd-catalyzed cross-couplings with aryl bromides and iodides in the presence of TBAF in toluene with addition of the measured amount of water. One chloride ligand on the Ge center allows efficient activation by fluoride to promote transfer of one, two, or three phenyl groups from the organogermane precursors.

  • 卷 12
  • 期 4
  • 页码 816-819
  • American Chemical Society
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