array(2) { ["lab"]=> string(2) "98" ["publication"]=> string(4) "7715" } Reactivity of hydropersulfides toward the hydroxyl radical unraveled: disulfide bond cleavage, hydrogen atom transfer, and proton-coupled electron transfer - 瑕瑜研究组-自由基生物质谱 | LabXing

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Reactivity of hydropersulfides toward the hydroxyl radical unraveled: disulfide bond cleavage, hydrogen atom transfer, and proton-coupled electron transfer

2018
期刊 Physical Chemistry Chemical Physics
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Hydropersulfides (RSSH) are highly reactive towards OH radical, and depending on the nature of R substitute, a selective OH substitution with S–S bond cleavage competes with the hydrogen abstraction by the radical.

  • 卷 20
  • 期 7
  • 页码 4793-4804
  • Royal Society of Chemistry (RSC)
  • ISSN: 1463-9076
  • DOI: 10.1039/c7cp07570g