Theoretical Study on the Reactions of (CF3)2CFOCH3 + OH/Cl and Reaction of (CF3)2CFOCHO with Cl Atom - 白凤杨

Reactions of (CF3)2CFOCH3 and (CF3)2CFOCHO with hydroxyl radical and chlorine atom are studied at the B3LYP and BHandHLYP/6-311+G(d,p) levels along with the geometries and frequencies of all stationary points. This study is further refined by CCSD(T) and QCISD(T)/6-311+G(d,p) methods in the minimum energy paths. For the reaction (CF3)2CFOCH3 + OH, two hydrogen abstraction channels are found. The total rate constants for the reactions (CF3)2CFOCH3 + OH/Cl and (CF3)2CFOCHO + Cl are followed by means of the canonical variational transition state with the small-curvature tunneling correction. The comparison between the hydrogen abstraction rate constants by hydroxyl and chlorine atom is discussed. Calculated rate constants are in reasonable agreement with the available experiment data. The standard enthalpies of formation for the reactants, (CF3)2CFOCH3 and (CF3)2CFOCHO, and two products, (CF3)2CFOCH2 and (CF3)2CFOCO, are evaluated by a series of isodesmic reactions. The Arrhenius expressions for the title reactions are given as follows: k1= 1.08 × 10–22 T3.38 exp(−213.31/T), k2= 3.55 × 10–22 T3.61 exp(−240.26/T), and k3= 3.00 × 10 –19 T2.58 exp(−1294.34/T) cm3 molecule–1 s–1.