array(2) { ["lab"]=> string(3) "672" ["publication"]=> string(4) "4069" } Competition between weak hydrogen bonds: C–H⋯Cl is preferred to C–H⋯F in CH2ClF–H2CO, as revealed by rotational spectroscopy - Group of Molecular Spectrocopy | LabXing

Group of Molecular Spectrocopy

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大学 重庆大学 / 化学化工学院
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Competition between weak hydrogen bonds: C–H⋯Cl is preferred to C–H⋯F in CH2ClF–H2CO, as revealed by rotational spectroscopy

2014
期刊 Phys. Chem. Chem. Phys.
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CH2O is linked to CH2ClF through a C–H⋯Cl weak hydrogen bond, and it rotates along its symmetry axis with a barrier V2 ∼ 125 cm−1.

  • 卷 16
  • 期 24
  • 页码 12261-12265
  • Royal Society of Chemistry (RSC)
  • ISSN: 1463-9076
  • DOI: 10.1039/c4cp00919c
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