array(2) { ["lab"]=> string(3) "586" ["publication"]=> string(4) "4861" } Divergent Protosilylation and Protoborylation of Polar Enynes - 姜兵 | LabXing

姜兵

简介

大学 安徽科技学院 / 化学与材料工程学院
关注
分享到

Divergent Protosilylation and Protoborylation of Polar Enynes

2019
期刊 Organic Letters
Copper-catalyzed divergent conjugate protosilylation and protoborylation of polar enynes were developed. The corresponding β-boryldienoates and β-silyldienotes were obtained in moderate to good yields and with good stereoselectivity. In this protocol, novel cascade double protoborylation/protodeboronation processes of polar enynoates enabled access of the useful trisubstituted vinylboronates in up to 80% yield and with up to 98:2 Z/E ratio. Moreover, divergent transformations of the products thus obtained were also investigated.

  • DOI: 10.1021/acs.orglett.9b00995
LabXing 上可以免费创建课题组网站
© LabXing 2018 关于LabXing 帮助中心 testing.service 京公网安备11010802025734号