array(2) { ["lab"]=> string(3) "361" ["publication"]=> string(4) "4732" } Silver-Catalyzed C–H Trifluoromethylation of Arenes Using Trifluoroacetic Acid as the Trifluoromethylating Reagent - 张扬会课题组 | LabXing

Silver-Catalyzed C–H Trifluoromethylation of Arenes Using Trifluoroacetic Acid as the Trifluoromethylating Reagent

2015
期刊 Organic Letters
Direct trifluoromethylation of arenes using TFA as the trifluoromethylating reagent was achieved with Ag as the catalyst. This reaction not only provides a new protocol for aryl C–H trifluoromethylation, but the generation of CF3· from TFA may prove useful in other contexts and could potentially be extended to other trifluoromethylation reactions.

  • 卷 17
  • 期 1
  • 页码 38-41
  • American Chemical Society (ACS)
  • ISSN: 1523-7060
  • DOI: 10.1021/ol503189j