array(2) { ["lab"]=> string(3) "361" ["publication"]=> string(4) "4729" } Palladium-catalyzed sequential three-component reactions to access vinylsilanes - 张扬会课题组 | LabXing

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大学 同济大学 / 化学科学与工程学院
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Palladium-catalyzed sequential three-component reactions to access vinylsilanes

2018
期刊 Chemical Communications
A palladium-catalyzed sequential three-component reaction has been developed. The palladacycles, generated through cascade reactions of aryl halides and alkynes, are the key intermediates and react with hexamethyldisilane to form disilylated products. The reaction represents a useful preparative method for vinylsilanes, and the vinylsilanes can be transformed into tetrasubstituted alkenes.

  • 卷 54
  • 期 75
  • 页码 10598-10601
  • Royal Society of Chemistry (RSC)
  • ISSN: 1359-7345
  • DOI: 10.1039/c8cc05254a
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