Synthesis of Triphenylenes Starting from 2-Iodobiphenyls and Iodobenzenes via Palladium-Catalyzed Dual C–H Activation and Double C–C Bond Formation

array(2) { ["lab"]=> string(3) "361" ["publication"]=> string(4) "4718" } Synthesis of Triphenylenes Starting from 2-Iodobiphenyls and Iodobenzenes via Palladium-Catalyzed Dual C–H Activation and Double C–C Bond Formation - 张扬会课题组 | LabXing

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2017

期刊 Organic Letters

作者 Shulei Pan · Hang Jiang · Yu Zhang · Dushen Chen · Yanghui Zhang

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A novel and facile approach for the synthesis of triphenylenes has been developed via palladium-catalyzed coupling of 2-iodobiphenyls and iodobenzenes. The reaction involves dual palladium-catalyzed C–H activations and double palladium-catalyzed C–C bond formations. A range of unsymmetrically functionalized triphenylenes can be synthesized with the reaction. The approach features readily available starting materials, high atom- and step-economy, and access to various unsymmetrically functionalized triphenylenes.

卷 18
期 20
页码 5192-5195
American Chemical Society (ACS)
ISSN: 1523-7060
DOI: 10.1021/acs.orglett.6b02071

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