array(2) { ["lab"]=> string(4) "1311" ["publication"]=> string(5) "11285" } Catalytic asymmetric trifluoromethylthiolation of carbonyl compounds via a diastereo and enantioselective Cu-catalyzed tandem reaction - 汪君课题组 | LabXing

汪君课题组

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大学 香港浸会大学 / 化学系
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Catalytic asymmetric trifluoromethylthiolation of carbonyl compounds via a diastereo and enantioselective Cu-catalyzed tandem reaction

2018
期刊 Chemical Communications
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The tandem reaction realizes the asymmetric integration of –SCF3 group to carbonyl compounds, establishing the chiral tertiary α-carbon center and affording the α-SCF3-β-substituted carbonyl compounds in 50–92% yields with up to 20 : 1 dr and 96% ee.

  • 卷 54
  • 期 36
  • 页码 4581-4584
  • Royal Society of Chemistry (RSC)
  • ISSN: 1359-7345
  • DOI: 10.1039/c8cc02097c
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